Soluble lanthanide salts (LnCl3,·2 LiCl) for the improved addition of organomagnesium reagents to carbonyl compounds

Arkady Krasovskiy, Felix Kopp, Paul Knochel

Research output: Contribution to journalArticle

185 Citations (Scopus)

Abstract

(Chemical Equation Presented) Easy-to-prepare solutions of LnCl 3·2 LiCl (Ln = La, Ce, Nd) (0.3-0.5 M in THF) are a unique source of soluble lanthanide salts with versatile applications in organic synthesis. These salts can serve as promoters or catalysts for the addition of organometallic compounds to sterically hindered, enolizable or α,β-unsaturated ketones or imines.

Original languageEnglish (US)
Pages (from-to)497-500
Number of pages4
JournalAngewandte Chemie - International Edition
Volume45
Issue number3
DOIs
StatePublished - Jan 9 2006
Externally publishedYes

Fingerprint

Carbonyl compounds
Lanthanoid Series Elements
Rare earth elements
Salts
Organometallic Compounds
Imines
Organometallics
Ketones
Catalysts

Keywords

  • 1,2-additions
  • Enols
  • Grignard reaction
  • Imines
  • Lanthanides

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Soluble lanthanide salts (LnCl3,·2 LiCl) for the improved addition of organomagnesium reagents to carbonyl compounds. / Krasovskiy, Arkady; Kopp, Felix; Knochel, Paul.

In: Angewandte Chemie - International Edition, Vol. 45, No. 3, 09.01.2006, p. 497-500.

Research output: Contribution to journalArticle

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