Raman scattering and infrared absorption from the C-N stretching modes of K2Pt(CN)4Br0.3 3H2O

D. L. Rousseau; M. A. Butler; H. J. Guggenheim; R. B. Weisman; A. N. Bloch

doi:10.1103/PhysRevB.10.2281

Raman scattering and infrared absorption from the C-N stretching modes of K2Pt(CN)4Br0.3 3H2O

D. L. Rousseau, M. A. Butler, H. J. Guggenheim, R. B. Weisman, A. N. Bloch

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13 Scopus citations

Abstract

We have carefully measured the Raman scattering and infrared absorption spectra of the C-N stretching region of K2Pt(CN)4Br0.3 3H2O. The expected polarization differences between B1g and B2g modes were observed along with a large frequency splitting between the modes. We attribute this frequency splitting to significant differences in the environment of the two platinum sites in the crystallographic unit cell.

Original language	English (US)
Pages (from-to)	2281-2285
Number of pages	5
Journal	Physical Review B
Volume	10
Issue number	6
DOIs	https://doi.org/10.1103/PhysRevB.10.2281
State	Published - 1974
Externally published	Yes

ASJC Scopus subject areas

Condensed Matter Physics

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10.1103/PhysRevB.10.2281

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title = "Raman scattering and infrared absorption from the C-N stretching modes of K2Pt(CN)4Br0.3 3H2O",

abstract = "We have carefully measured the Raman scattering and infrared absorption spectra of the C-N stretching region of K2Pt(CN)4Br0.3 3H2O. The expected polarization differences between B1g and B2g modes were observed along with a large frequency splitting between the modes. We attribute this frequency splitting to significant differences in the environment of the two platinum sites in the crystallographic unit cell.",

author = "Rousseau, {D. L.} and Butler, {M. A.} and Guggenheim, {H. J.} and Weisman, {R. B.} and Bloch, {A. N.}",

year = "1974",

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T1 - Raman scattering and infrared absorption from the C-N stretching modes of K2Pt(CN)4Br0.3 3H2O

AU - Rousseau, D. L.

AU - Butler, M. A.

AU - Guggenheim, H. J.

AU - Weisman, R. B.

AU - Bloch, A. N.

PY - 1974

Y1 - 1974

N2 - We have carefully measured the Raman scattering and infrared absorption spectra of the C-N stretching region of K2Pt(CN)4Br0.3 3H2O. The expected polarization differences between B1g and B2g modes were observed along with a large frequency splitting between the modes. We attribute this frequency splitting to significant differences in the environment of the two platinum sites in the crystallographic unit cell.

AB - We have carefully measured the Raman scattering and infrared absorption spectra of the C-N stretching region of K2Pt(CN)4Br0.3 3H2O. The expected polarization differences between B1g and B2g modes were observed along with a large frequency splitting between the modes. We attribute this frequency splitting to significant differences in the environment of the two platinum sites in the crystallographic unit cell.

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DO - 10.1103/PhysRevB.10.2281

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ER -

Raman scattering and infrared absorption from the C-N stretching modes of K2Pt(CN)4Br0.3 3H2O

Abstract

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