Raman scattering and infrared absorption from the C-N stretching modes of K2Pt(CN)4Br0.3 3H2O

D. L. Rousseau, M. A. Butler, H. J. Guggenheim, R. B. Weisman, A. N. Bloch

Research output: Contribution to journalArticlepeer-review

12 Scopus citations

Abstract

We have carefully measured the Raman scattering and infrared absorption spectra of the C-N stretching region of K2Pt(CN)4Br0.3 3H2O. The expected polarization differences between B1g and B2g modes were observed along with a large frequency splitting between the modes. We attribute this frequency splitting to significant differences in the environment of the two platinum sites in the crystallographic unit cell.

Original languageEnglish (US)
Pages (from-to)2281-2285
Number of pages5
JournalPhysical Review B
Volume10
Issue number6
DOIs
StatePublished - Jan 1 1974
Externally publishedYes

ASJC Scopus subject areas

  • Condensed Matter Physics

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