X-ray photoelectron measurements of one-dimensional platinum compounds

M. A. Butler; D. L. Rousseau; D. N.E. Buchanan

doi:10.1103/PhysRevB.7.61

X-ray photoelectron measurements of one-dimensional platinum compounds

M. A. Butler, D. L. Rousseau, D. N.E. Buchanan

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12 Scopus citations

Abstract

The x-ray photoemission spectra (XPS) of the series of compounds K2Pt(CN)4X0.3•nH2O, where X=Cl and Br, have been measured. Satellites are observed on the Pt(4f), N(1s), and C(1s) lines and are shown to arise from simultaneous excitation of the Pt(CN)4 complex during photoemission. The positions and widths of the Pt(4f) levels indicate that the Pt(5dz2) electrons are delocalized with a variation of electron density between any two Pt sites being 0.2 electrons.

Original language	English (US)
Pages (from-to)	61-65
Number of pages	5
Journal	Physical Review B
Volume	7
Issue number	1
DOIs	https://doi.org/10.1103/PhysRevB.7.61
State	Published - 1973
Externally published	Yes

ASJC Scopus subject areas

Condensed Matter Physics

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10.1103/PhysRevB.7.61

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title = "X-ray photoelectron measurements of one-dimensional platinum compounds",

abstract = "The x-ray photoemission spectra (XPS) of the series of compounds K2Pt(CN)4X0.3•nH2O, where X=Cl and Br, have been measured. Satellites are observed on the Pt(4f), N(1s), and C(1s) lines and are shown to arise from simultaneous excitation of the Pt(CN)4 complex during photoemission. The positions and widths of the Pt(4f) levels indicate that the Pt(5dz2) electrons are delocalized with a variation of electron density between any two Pt sites being 0.2 electrons.",

author = "Butler, {M. A.} and Rousseau, {D. L.} and Buchanan, {D. N.E.}",

year = "1973",

doi = "10.1103/PhysRevB.7.61",

language = "English (US)",

volume = "7",

pages = "61--65",

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T1 - X-ray photoelectron measurements of one-dimensional platinum compounds

AU - Butler, M. A.

AU - Rousseau, D. L.

AU - Buchanan, D. N.E.

PY - 1973

Y1 - 1973

N2 - The x-ray photoemission spectra (XPS) of the series of compounds K2Pt(CN)4X0.3•nH2O, where X=Cl and Br, have been measured. Satellites are observed on the Pt(4f), N(1s), and C(1s) lines and are shown to arise from simultaneous excitation of the Pt(CN)4 complex during photoemission. The positions and widths of the Pt(4f) levels indicate that the Pt(5dz2) electrons are delocalized with a variation of electron density between any two Pt sites being 0.2 electrons.

AB - The x-ray photoemission spectra (XPS) of the series of compounds K2Pt(CN)4X0.3•nH2O, where X=Cl and Br, have been measured. Satellites are observed on the Pt(4f), N(1s), and C(1s) lines and are shown to arise from simultaneous excitation of the Pt(CN)4 complex during photoemission. The positions and widths of the Pt(4f) levels indicate that the Pt(5dz2) electrons are delocalized with a variation of electron density between any two Pt sites being 0.2 electrons.

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U2 - 10.1103/PhysRevB.7.61

DO - 10.1103/PhysRevB.7.61

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SP - 61

EP - 65

JO - Physical Review B

JF - Physical Review B

IS - 1

ER -

X-ray photoelectron measurements of one-dimensional platinum compounds

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