X-ray photoelectron measurements of one-dimensional platinum compounds

M. A. Butler, Denis L. Rousseau, D. N E Buchanan

Research output: Contribution to journalArticle

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Abstract

The x-ray photoemission spectra (XPS) of the series of compounds K2Pt(CN)4X0.3•nH2O, where X=Cl and Br, have been measured. Satellites are observed on the Pt(4f), N(1s), and C(1s) lines and are shown to arise from simultaneous excitation of the Pt(CN)4 complex during photoemission. The positions and widths of the Pt(4f) levels indicate that the Pt(5dz2) electrons are delocalized with a variation of electron density between any two Pt sites being 0.2 electrons.

Original languageEnglish (US)
Pages (from-to)61-65
Number of pages5
JournalPhysical Review B
Volume7
Issue number1
DOIs
StatePublished - 1973
Externally publishedYes

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platinum compounds
photoelectrons
photoelectric emission
electrons
x rays
excitation

ASJC Scopus subject areas

  • Condensed Matter Physics

Cite this

X-ray photoelectron measurements of one-dimensional platinum compounds. / Butler, M. A.; Rousseau, Denis L.; Buchanan, D. N E.

In: Physical Review B, Vol. 7, No. 1, 1973, p. 61-65.

Research output: Contribution to journalArticle

Butler, M. A. ; Rousseau, Denis L. ; Buchanan, D. N E. / X-ray photoelectron measurements of one-dimensional platinum compounds. In: Physical Review B. 1973 ; Vol. 7, No. 1. pp. 61-65.
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