Synthesis and structure of [BpBut,Pri]2Co: A bis(pyrazolyl)hydroborato cobalt(II) complex with trans [Co⋯H-B] interactions

Prasenjit Ghosh, Jeffrey B. Bonanno, Gerard Parkin

Research output: Contribution to journalArticle

19 Scopus citations

Abstract

The bis{bis(3-tert-butyl-5-isopropylpyrazolyl)hydroborato}-cobalt(II) complex [BpBut,Pri]2Co has been synthesized by reaction of Tl[BpBut,Pri] with Co(ClO4)2·6H2O; the molecular structure of [BpBut,Pri]2Co is based on a square planar array of pyrazolyl groups with two axial [Co⋯H-B] interactions, in marked contrast to those of other [BpR,R′]2Co derivatives which have tetrahedral structures and are devoid of such interactions.

Original languageEnglish (US)
Pages (from-to)2779-2781
Number of pages3
JournalJournal of the Chemical Society - Dalton Transactions
Issue number17
DOIs
StatePublished - Jan 1 1998
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)

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