Synthesis and characterization of nanosized metals embedded in polystyrene matrix

Devinder Mahajan, Amruta Desai, Miriam Rafailovich, Min-Hui Cui, Nan Loh Yang

Research output: Contribution to journalArticle

16 Citations (Scopus)

Abstract

Thermal treatment of a solution containing iron pentacarbonyl and styrene monomer in hexadecane resulted in a high yield (>90%) of nanoparticles of iron encapsulated in a polystyrene matrix (Fe-PST). The freshly prepared off-colored Fe in polystyrene (Fe-PST) material consisted of black particles that were attributed to zero-valent iron. On exposure to air, the black Fe particles slowly turned dark brown due to conversion into iron oxide. The observed oxidation phenomenon was confirmed by electron paramagnetic resonance (EPR) spectroscopy: the freshly prepared Fe-PST was EPR silent but after exposure to air, a strong signature EPR signal for iron oxide was recorded. The infrared data confirmed changes in intensity of characteristic bands of PST in Fe-PST. The TEM image of the oxidized Fe-PST material consisted of discrete Fe particles that were distributed throughout the polymer matrix. The differential scanning calorimetric data of Fe-PST showed an enhanced glass transition temperature to 120 °C owing to the presence of Fe nanoparticles.

Original languageEnglish (US)
Pages (from-to)74-80
Number of pages7
JournalComposites Part B: Engineering
Volume37
Issue number1
DOIs
StatePublished - Jan 2006
Externally publishedYes

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Polystyrenes
Metals
Paramagnetic resonance
Iron
Iron oxides
Nanoparticles
Styrene
Air
Polymer matrix
Monomers
Heat treatment
Spectroscopy
Transmission electron microscopy
Infrared radiation
Scanning
Oxidation

Keywords

  • Nano metal particles

ASJC Scopus subject areas

  • Engineering(all)
  • Ceramics and Composites

Cite this

Synthesis and characterization of nanosized metals embedded in polystyrene matrix. / Mahajan, Devinder; Desai, Amruta; Rafailovich, Miriam; Cui, Min-Hui; Yang, Nan Loh.

In: Composites Part B: Engineering, Vol. 37, No. 1, 01.2006, p. 74-80.

Research output: Contribution to journalArticle

Mahajan, Devinder ; Desai, Amruta ; Rafailovich, Miriam ; Cui, Min-Hui ; Yang, Nan Loh. / Synthesis and characterization of nanosized metals embedded in polystyrene matrix. In: Composites Part B: Engineering. 2006 ; Vol. 37, No. 1. pp. 74-80.
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