Resonant raman scattering from iodine: Spectral changes with excitation frequency

P. F. Williams; D. L. Rousseau

doi:10.1103/PhysRevLett.30.951

Resonant raman scattering from iodine: Spectral changes with excitation frequency

P. F. Williams, D. L. Rousseau

Research output: Contribution to journal › Article › peer-review

45 Scopus citations

Abstract

We have recorded high-resolution resonant Raman spectra of molecular iodine which show very pronounced systematic spectral band-shape variations with incident laser frequency. This frequency dependence and the presence of the multiple overtones in resonant Raman scattering from iodine may be explained by a theory in which the scattering intensity depends on Franck-Condon overlap integrals. We have obtained semi-quantitative agreement between the observed spectra and spectra calculated from this theory.

Original language	English (US)
Pages (from-to)	951-954
Number of pages	4
Journal	Physical Review Letters
Volume	30
Issue number	20
DOIs	https://doi.org/10.1103/PhysRevLett.30.951
State	Published - 1973
Externally published	Yes

ASJC Scopus subject areas

General Physics and Astronomy

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10.1103/PhysRevLett.30.951

Cite this

@article{c47efef892a5446999ce5a5b976d6deb,

title = "Resonant raman scattering from iodine: Spectral changes with excitation frequency",

abstract = "We have recorded high-resolution resonant Raman spectra of molecular iodine which show very pronounced systematic spectral band-shape variations with incident laser frequency. This frequency dependence and the presence of the multiple overtones in resonant Raman scattering from iodine may be explained by a theory in which the scattering intensity depends on Franck-Condon overlap integrals. We have obtained semi-quantitative agreement between the observed spectra and spectra calculated from this theory.",

author = "Williams, {P. F.} and Rousseau, {D. L.}",

year = "1973",

doi = "10.1103/PhysRevLett.30.951",

language = "English (US)",

volume = "30",

pages = "951--954",

journal = "Physical Review Letters",

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publisher = "American Physical Society",

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T2 - Spectral changes with excitation frequency

AU - Williams, P. F.

AU - Rousseau, D. L.

PY - 1973

Y1 - 1973

N2 - We have recorded high-resolution resonant Raman spectra of molecular iodine which show very pronounced systematic spectral band-shape variations with incident laser frequency. This frequency dependence and the presence of the multiple overtones in resonant Raman scattering from iodine may be explained by a theory in which the scattering intensity depends on Franck-Condon overlap integrals. We have obtained semi-quantitative agreement between the observed spectra and spectra calculated from this theory.

AB - We have recorded high-resolution resonant Raman spectra of molecular iodine which show very pronounced systematic spectral band-shape variations with incident laser frequency. This frequency dependence and the presence of the multiple overtones in resonant Raman scattering from iodine may be explained by a theory in which the scattering intensity depends on Franck-Condon overlap integrals. We have obtained semi-quantitative agreement between the observed spectra and spectra calculated from this theory.

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DO - 10.1103/PhysRevLett.30.951

M3 - Article

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JO - Physical Review Letters

JF - Physical Review Letters

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Resonant raman scattering from iodine: Spectral changes with excitation frequency

Abstract

ASJC Scopus subject areas

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