Molecular complexes of explosives with cyclodextrins. 2. Preparation and characterization of a solid complex of β-cyclodextrin with the nitramine 1,3,3-trinitroazetidine (TNAZ)

Sean M. Cahill, A. G. Rinzler, F. J. Owens, S. Bulusu

Research output: Contribution to journalArticle

12 Citations (Scopus)

Abstract

A solid complex between 1,3,3-trinitroazetidine (TNAZ) and β-cyclodextrin has been isolated for the first time and characterized by the application of solution and solid-state NMR techniques, Raman spectroscopy, and differential scanning calorimetry experiments. All the techniques show clear differences in properties of the solid product from those of a simple physical mixture of the components, and when taken together, they provide convincing evidence for the complex formation.

Original languageEnglish (US)
Pages (from-to)7095-7100
Number of pages6
JournalJournal of Physical Chemistry
Volume98
Issue number28
StatePublished - 1994
Externally publishedYes

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Cyclodextrins
preparation
heat measurement
Raman spectroscopy
solid state
nuclear magnetic resonance
scanning
Differential scanning calorimetry
products
Nuclear magnetic resonance
nitramine
1,3,3-Trinitroazetidine
Experiments

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry

Cite this

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abstract = "A solid complex between 1,3,3-trinitroazetidine (TNAZ) and β-cyclodextrin has been isolated for the first time and characterized by the application of solution and solid-state NMR techniques, Raman spectroscopy, and differential scanning calorimetry experiments. All the techniques show clear differences in properties of the solid product from those of a simple physical mixture of the components, and when taken together, they provide convincing evidence for the complex formation.",
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AU - Rinzler, A. G.

AU - Owens, F. J.

AU - Bulusu, S.

PY - 1994

Y1 - 1994

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AB - A solid complex between 1,3,3-trinitroazetidine (TNAZ) and β-cyclodextrin has been isolated for the first time and characterized by the application of solution and solid-state NMR techniques, Raman spectroscopy, and differential scanning calorimetry experiments. All the techniques show clear differences in properties of the solid product from those of a simple physical mixture of the components, and when taken together, they provide convincing evidence for the complex formation.

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