[Me2Si] ansa bridged complexes of permethyltitanocene: Synthesis and structural characterization of fulvene derivatives with trialkylidenemethane character

Hyosun Lee, Jeffrey B. Bonanno, Tony Hascall, Joseph Cordaro, Juliet M. Hahn, Gerard Parkin

Research output: Contribution to journalArticle

39 Citations (Scopus)

Abstract

A series of permethylated [Me2Si] ansa bridged titanocene complexes has been synthesized and structurally characterized by X-ray diffraction; the dialkyl complexes [Me2Si(C5Me4)]TiR2 are thermally unstable towards elimination of alkane (RH), thereby yielding fulvene derivatives [Me2Si(C5Me4)(C5Me 3CH2)]TiR.

Original languageEnglish (US)
Pages (from-to)1365-1368
Number of pages4
JournalJournal of the Chemical Society, Dalton Transactions
Issue number9
StatePublished - May 7 1999
Externally publishedYes

Fingerprint

Alkanes
Derivatives
X ray diffraction
fulvene
titanocene

ASJC Scopus subject areas

  • Inorganic Chemistry

Cite this

[Me2Si] ansa bridged complexes of permethyltitanocene : Synthesis and structural characterization of fulvene derivatives with trialkylidenemethane character. / Lee, Hyosun; Bonanno, Jeffrey B.; Hascall, Tony; Cordaro, Joseph; Hahn, Juliet M.; Parkin, Gerard.

In: Journal of the Chemical Society, Dalton Transactions, No. 9, 07.05.1999, p. 1365-1368.

Research output: Contribution to journalArticle

@article{f0cc9a8d7e5d46b4a24807a455ff0108,
title = "[Me2Si] ansa bridged complexes of permethyltitanocene: Synthesis and structural characterization of fulvene derivatives with trialkylidenemethane character",
abstract = "A series of permethylated [Me2Si] ansa bridged titanocene complexes has been synthesized and structurally characterized by X-ray diffraction; the dialkyl complexes [Me2Si(C5Me4)]TiR2 are thermally unstable towards elimination of alkane (RH), thereby yielding fulvene derivatives [Me2Si(C5Me4)(C5Me 3CH2)]TiR.",
author = "Hyosun Lee and Bonanno, {Jeffrey B.} and Tony Hascall and Joseph Cordaro and Hahn, {Juliet M.} and Gerard Parkin",
year = "1999",
month = "5",
day = "7",
language = "English (US)",
pages = "1365--1368",
journal = "Journal of the Chemical Society. Dalton Transactions",
issn = "1470-479X",
publisher = "Royal Society of Chemistry",
number = "9",

}

TY - JOUR

T1 - [Me2Si] ansa bridged complexes of permethyltitanocene

T2 - Synthesis and structural characterization of fulvene derivatives with trialkylidenemethane character

AU - Lee, Hyosun

AU - Bonanno, Jeffrey B.

AU - Hascall, Tony

AU - Cordaro, Joseph

AU - Hahn, Juliet M.

AU - Parkin, Gerard

PY - 1999/5/7

Y1 - 1999/5/7

N2 - A series of permethylated [Me2Si] ansa bridged titanocene complexes has been synthesized and structurally characterized by X-ray diffraction; the dialkyl complexes [Me2Si(C5Me4)]TiR2 are thermally unstable towards elimination of alkane (RH), thereby yielding fulvene derivatives [Me2Si(C5Me4)(C5Me 3CH2)]TiR.

AB - A series of permethylated [Me2Si] ansa bridged titanocene complexes has been synthesized and structurally characterized by X-ray diffraction; the dialkyl complexes [Me2Si(C5Me4)]TiR2 are thermally unstable towards elimination of alkane (RH), thereby yielding fulvene derivatives [Me2Si(C5Me4)(C5Me 3CH2)]TiR.

UR - http://www.scopus.com/inward/record.url?scp=33749100561&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=33749100561&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:33749100561

SP - 1365

EP - 1368

JO - Journal of the Chemical Society. Dalton Transactions

JF - Journal of the Chemical Society. Dalton Transactions

SN - 1470-479X

IS - 9

ER -