[Me2Si] ansa bridged complexes of permethyltitanocene

Synthesis and structural characterization of fulvene derivatives with trialkylidenemethane character

Hyosun Lee, Jeffrey B. Bonanno, Tony Hascall, Joseph Cordaro, Juliet M. Hahn, Gerard Parkin

Research output: Contribution to journalArticle

39 Citations (Scopus)

Abstract

A series of permethylated [Me2Si] ansa bridged titanocene complexes has been synthesized and structurally characterized by X-ray diffraction; the dialkyl complexes [Me2Si(C5Me4)]TiR2 are thermally unstable towards elimination of alkane (RH), thereby yielding fulvene derivatives [Me2Si(C5Me4)(C5Me 3CH2)]TiR.

Original languageEnglish (US)
Pages (from-to)1365-1368
Number of pages4
JournalJournal of the Chemical Society, Dalton Transactions
Issue number9
StatePublished - May 7 1999
Externally publishedYes

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Alkanes
Derivatives
X ray diffraction
fulvene
titanocene

ASJC Scopus subject areas

  • Inorganic Chemistry

Cite this

[Me2Si] ansa bridged complexes of permethyltitanocene : Synthesis and structural characterization of fulvene derivatives with trialkylidenemethane character. / Lee, Hyosun; Bonanno, Jeffrey B.; Hascall, Tony; Cordaro, Joseph; Hahn, Juliet M.; Parkin, Gerard.

In: Journal of the Chemical Society, Dalton Transactions, No. 9, 07.05.1999, p. 1365-1368.

Research output: Contribution to journalArticle

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