[Me2Si] ansa bridged complexes of permethyltitanocene: Synthesis and structural characterization of fulvene derivatives with trialkylidenemethane character

Hyosun Lee, Jeffrey B. Bonanno, Tony Hascall, Joseph Cordaro, Juliet M. Hahn, Gerard Parkin

Research output: Contribution to journalArticlepeer-review

41 Scopus citations

Abstract

A series of permethylated [Me2Si] ansa bridged titanocene complexes has been synthesized and structurally characterized by X-ray diffraction; the dialkyl complexes [Me2Si(C5Me4)]TiR2 are thermally unstable towards elimination of alkane (RH), thereby yielding fulvene derivatives [Me2Si(C5Me4)(C5Me 3CH2)]TiR.

Original languageEnglish (US)
Pages (from-to)1365-1368
Number of pages4
JournalJournal of the Chemical Society - Dalton Transactions
Issue number9
DOIs
StatePublished - May 7 1999
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)

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