A series of permethylated [Me2Si] ansa bridged titanocene complexes has been synthesized and structurally characterized by X-ray diffraction; the dialkyl complexes [Me2Si(C5Me4)]TiR2 are thermally unstable towards elimination of alkane (RH), thereby yielding fulvene derivatives [Me2Si(C5Me4)(C5Me 3CH2)]TiR.
|Original language||English (US)|
|Number of pages||4|
|Journal||Journal of the Chemical Society - Dalton Transactions|
|State||Published - May 7 1999|
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