Lasalocid crystallized from methanol: Spectroscopic and x-ray structural evidence for two structures

Joe M. Friedman, Denis L. Rousseau, Cynthia Shen, Chian C. Chiang, Eileen N. Duesler, Iain C. Paul

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Abstract

Results of i.r. absorption and Raman scattering data and X-ray crystallographic data for lasalocid crystallized from methanol have enabled identification of two distinct structures for the 1: 1 lasalocid-methanolate complex. Both have space group P212121 but possess a different molecular geometry. The ketone carbonyl stretching frequency in the 1 700-1 730 cm-1 region is a sensitive indicator of crystalline modification.

Original languageEnglish (US)
Pages (from-to)835-838
Number of pages4
JournalJournal of the Chemical Society, Perkin Transactions 2
Issue number6
DOIs
Publication statusPublished - Jan 1 1979
Externally publishedYes

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ASJC Scopus subject areas

  • Chemistry(all)

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