Hydrogen bonding between solvation shells around gd3+ from cooperative vibronic spectra

Michael Stavola; J. M. Friedman; R. A. Stepnoski; Mark G. Sceats

doi:10.1016/0009-2614(81)80087-5

Hydrogen bonding between solvation shells around gd³⁺ from cooperative vibronic spectra

Michael Stavola, J. M. Friedman, R. A. Stepnoski, Mark G. Sceats

Research output: Contribution to journal › Article › peer-review

27 Scopus citations

Abstract

Cooperative vibronic spectra involving Gd³⁺ electronic transitions and the vibrational transitions of nearby water molecules are used to determine the stretching spectrum for isotopically dilute OH in a solution of GdCl₃ in D₂O. The OH stretching spectrum of water molecules in the first hydration sphere is shifted to lower energy than that of the bulk liquid.

Original language	English (US)
Pages (from-to)	192-194
Number of pages	3
Journal	Chemical Physics Letters
Volume	80
Issue number	1
DOIs	https://doi.org/10.1016/0009-2614(81)80087-5
State	Published - May 15 1981
Externally published	Yes

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

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10.1016/0009-2614(81)80087-5

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title = "Hydrogen bonding between solvation shells around gd3+ from cooperative vibronic spectra",

abstract = "Cooperative vibronic spectra involving Gd3+ electronic transitions and the vibrational transitions of nearby water molecules are used to determine the stretching spectrum for isotopically dilute OH in a solution of GdCl3 in D2O. The OH stretching spectrum of water molecules in the first hydration sphere is shifted to lower energy than that of the bulk liquid.",

author = "Michael Stavola and Friedman, {J. M.} and Stepnoski, {R. A.} and Sceats, {Mark G.}",

year = "1981",

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AU - Friedman, J. M.

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AU - Sceats, Mark G.

PY - 1981/5/15

Y1 - 1981/5/15

N2 - Cooperative vibronic spectra involving Gd3+ electronic transitions and the vibrational transitions of nearby water molecules are used to determine the stretching spectrum for isotopically dilute OH in a solution of GdCl3 in D2O. The OH stretching spectrum of water molecules in the first hydration sphere is shifted to lower energy than that of the bulk liquid.

AB - Cooperative vibronic spectra involving Gd3+ electronic transitions and the vibrational transitions of nearby water molecules are used to determine the stretching spectrum for isotopically dilute OH in a solution of GdCl3 in D2O. The OH stretching spectrum of water molecules in the first hydration sphere is shifted to lower energy than that of the bulk liquid.

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Hydrogen bonding between solvation shells around gd³⁺ from cooperative vibronic spectra

Abstract

ASJC Scopus subject areas

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