Hydrogen bonding between solvation shells around gd3+ from cooperative vibronic spectra

Michael Stavola, Joel M. Friedman, R. A. Stepnoski, Mark G. Sceats

Research output: Contribution to journalArticle

26 Citations (Scopus)

Abstract

Cooperative vibronic spectra involving Gd3+ electronic transitions and the vibrational transitions of nearby water molecules are used to determine the stretching spectrum for isotopically dilute OH in a solution of GdCl3 in D2O. The OH stretching spectrum of water molecules in the first hydration sphere is shifted to lower energy than that of the bulk liquid.

Original languageEnglish (US)
Pages (from-to)192-194
Number of pages3
JournalChemical Physics Letters
Volume80
Issue number1
DOIs
StatePublished - May 15 1981
Externally publishedYes

Fingerprint

Solvation
Stretching
solvation
Hydrogen bonds
Molecules
Water
hydrogen
Hydration
water
hydration
molecules
Liquids
liquids
electronics
energy

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Spectroscopy
  • Condensed Matter Physics
  • Atomic and Molecular Physics, and Optics
  • Surfaces and Interfaces

Cite this

Hydrogen bonding between solvation shells around gd3+ from cooperative vibronic spectra. / Stavola, Michael; Friedman, Joel M.; Stepnoski, R. A.; Sceats, Mark G.

In: Chemical Physics Letters, Vol. 80, No. 1, 15.05.1981, p. 192-194.

Research output: Contribution to journalArticle

Stavola, Michael ; Friedman, Joel M. ; Stepnoski, R. A. ; Sceats, Mark G. / Hydrogen bonding between solvation shells around gd3+ from cooperative vibronic spectra. In: Chemical Physics Letters. 1981 ; Vol. 80, No. 1. pp. 192-194.
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