High frequency (140 GHz) dynamic nuclear polarization: Polarization transfer to a solute in frozen aqueous solution

G. J. Gerfen, L. R. Becerra, D. A. Hall, R. G. Griffin, R. J. Temkin, D. J. Singel

Research output: Contribution to journalArticlepeer-review

143 Scopus citations

Abstract

Dynamic nuclear polarization (DNP) transfers the large polarization of unpaired electrons to nuclei and thus significantly enhances the signal strength in nuclear magnetic resonance (NMR) spectroscopy. High frequency/field (140 GHz/5 T) DNP has been implemented in solid state NMR experiments using a nitroxide radical as the paramagnetic polarizing agent in a watenglycerol frozen solution. The 1H and 13C NMR signal strengths of both the solvent and an amino acid solute have been enhanced by a factor of 185, which represents a reduction of >102 in sample size requirements or >104 in signal acquisition time.

Original languageEnglish (US)
Pages (from-to)9494-9497
Number of pages4
JournalThe Journal of Chemical Physics
Volume102
Issue number24
DOIs
StatePublished - Jan 1 1995
Externally publishedYes

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

Fingerprint Dive into the research topics of 'High frequency (140 GHz) dynamic nuclear polarization: Polarization transfer to a solute in frozen aqueous solution'. Together they form a unique fingerprint.

Cite this