Functionalized main-group organometallics for organic synthesis

Paul Knochel, Eike Hupe, Wolfgang Dohle, David M. Lindsay, Véronique Bonnet, Guy Quéguiner, Andreas Boudier, Felix Kopp, Stéphane Demay, Naka Seidel, M. Isabel Calaza, Viet Anh Vu, Ioannis Sapountzis, Tanasri Bunlaksananusorn

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

Highly functionalized Grignard-reagents can be easily obtained by an iodine-magnesim exchange reaction and further reacted with various electrophiles. Via a B-Zn exchange reaction, a formal Michael addition with umpolung of the reactivity can be achieved. Chiral phosphine ligands can be easily synthesized by a 2.3 sigmatropic rearrangement and used successfully in asymmetric synthesis.

Original languageEnglish (US)
Pages (from-to)11-17
Number of pages7
JournalPure and Applied Chemistry
Volume74
Issue number1
StatePublished - 2002
Externally publishedYes

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phosphine
Organometallics
Iodine
Ligands

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Knochel, P., Hupe, E., Dohle, W., Lindsay, D. M., Bonnet, V., Quéguiner, G., ... Bunlaksananusorn, T. (2002). Functionalized main-group organometallics for organic synthesis. Pure and Applied Chemistry, 74(1), 11-17.

Functionalized main-group organometallics for organic synthesis. / Knochel, Paul; Hupe, Eike; Dohle, Wolfgang; Lindsay, David M.; Bonnet, Véronique; Quéguiner, Guy; Boudier, Andreas; Kopp, Felix; Demay, Stéphane; Seidel, Naka; Calaza, M. Isabel; Vu, Viet Anh; Sapountzis, Ioannis; Bunlaksananusorn, Tanasri.

In: Pure and Applied Chemistry, Vol. 74, No. 1, 2002, p. 11-17.

Research output: Contribution to journalArticle

Knochel, P, Hupe, E, Dohle, W, Lindsay, DM, Bonnet, V, Quéguiner, G, Boudier, A, Kopp, F, Demay, S, Seidel, N, Calaza, MI, Vu, VA, Sapountzis, I & Bunlaksananusorn, T 2002, 'Functionalized main-group organometallics for organic synthesis', Pure and Applied Chemistry, vol. 74, no. 1, pp. 11-17.
Knochel P, Hupe E, Dohle W, Lindsay DM, Bonnet V, Quéguiner G et al. Functionalized main-group organometallics for organic synthesis. Pure and Applied Chemistry. 2002;74(1):11-17.
Knochel, Paul ; Hupe, Eike ; Dohle, Wolfgang ; Lindsay, David M. ; Bonnet, Véronique ; Quéguiner, Guy ; Boudier, Andreas ; Kopp, Felix ; Demay, Stéphane ; Seidel, Naka ; Calaza, M. Isabel ; Vu, Viet Anh ; Sapountzis, Ioannis ; Bunlaksananusorn, Tanasri. / Functionalized main-group organometallics for organic synthesis. In: Pure and Applied Chemistry. 2002 ; Vol. 74, No. 1. pp. 11-17.
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