Exploration of the "traceless" reductive ligation of S-nitrosothiols

Jiming Zhang; Hua Wang; Ming Xian

doi:10.1021/ol802663q

Exploration of the "traceless" reductive ligation of S-nitrosothiols

Jiming Zhang, Hua Wang, Ming Xian

Biochemistry

Research output: Contribution to journal › Article › peer-review

34 Scopus citations

Abstract

(Chemical Equation Presented) The first "traceless" reductive ligation of S-nitrosothiols using phosphine ester/thioester conjugates is reported. Experiments also show that stable thiolmidate compounds could be formed in the reaction between S-nitrosothiols and some phosphine-thioester substrates.

Original language	English (US)
Pages (from-to)	477-480
Number of pages	4
Journal	Organic Letters
Volume	11
Issue number	2
DOIs	https://doi.org/10.1021/ol802663q
State	Published - Jan 15 2009

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/ol802663q

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abstract = "(Chemical Equation Presented) The first {"}traceless{"} reductive ligation of S-nitrosothiols using phosphine ester/thioester conjugates is reported. Experiments also show that stable thiolmidate compounds could be formed in the reaction between S-nitrosothiols and some phosphine-thioester substrates.",

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AB - (Chemical Equation Presented) The first "traceless" reductive ligation of S-nitrosothiols using phosphine ester/thioester conjugates is reported. Experiments also show that stable thiolmidate compounds could be formed in the reaction between S-nitrosothiols and some phosphine-thioester substrates.

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Exploration of the "traceless" reductive ligation of S-nitrosothiols

Abstract

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