Convenient magnesiation of aromatic and heterocyclic rings bearing a hydroxy group in presence of LiCl

Felix Kopp, Arkady Krasovskiy, Paul Knochel

Research output: Contribution to journalArticle

58 Citations (Scopus)

Abstract

The reaction of various iodophenols with MeMgCl in presence of LiCl followed by the addition of i-PrMgCl provides the corresponding magnesiated magnesium phenolates as THF soluble reagents; this approach can be extended to heterocyclic compounds bearing a hydroxy group like pyridines and quinolines.

Original languageEnglish (US)
Pages (from-to)2288-2289
Number of pages2
JournalChemical Communications
Volume10
Issue number20
DOIs
StatePublished - Oct 21 2004
Externally publishedYes

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Bearings (structural)
Quinolines
Pyridines
Heterocyclic Compounds
Pyridine
Magnesium

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Convenient magnesiation of aromatic and heterocyclic rings bearing a hydroxy group in presence of LiCl. / Kopp, Felix; Krasovskiy, Arkady; Knochel, Paul.

In: Chemical Communications, Vol. 10, No. 20, 21.10.2004, p. 2288-2289.

Research output: Contribution to journalArticle

Kopp, Felix ; Krasovskiy, Arkady ; Knochel, Paul. / Convenient magnesiation of aromatic and heterocyclic rings bearing a hydroxy group in presence of LiCl. In: Chemical Communications. 2004 ; Vol. 10, No. 20. pp. 2288-2289.
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