Arylamine C-N bond oxidative addition to (silox)3Ta (silox = (t)Bu3SiO)

Jeffrey B. Bonanno, T. P. Henry, D. R. Neithamer, P. T. Wolczanski, E. B. Lobkovsky

Research output: Contribution to journalArticle

109 Citations (Scopus)

Abstract

Oxidative additions of carbon nitrogen and oxygen single bonds may be critical in the hydrodenitrogenation (HDN) and hydrodeoxygenation (HDO) of crude oil, yet few clear examples are evident. In support of such pathways, extensive investigations of transition metal-mediated C-N and C-O bond formations the microscopic reverse have recently been undertaken. While studying substituent effects on 1,2-H2elimination from (silox)3HTaN(H)(C6H4X) (silox = tBu4SiO) oxidative addition of H2NC6H4X to (silox)3Ta (1) deviated from the expected N-H cleavage. Oxidative additions of aryl C-N and related C-O bonds to 1 are reported herein.

Original languageEnglish (US)
Pages (from-to)5132-5133
Number of pages2
JournalJournal of the American Chemical Society
Volume118
Issue number21
DOIs
StatePublished - Jan 1 1996
Externally publishedYes

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Petroleum
Transition metals
Nitrogen
Carbon
Crude oil
Metals
Oxygen
single bond

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Arylamine C-N bond oxidative addition to (silox)3Ta (silox = (t)Bu3SiO). / Bonanno, Jeffrey B.; Henry, T. P.; Neithamer, D. R.; Wolczanski, P. T.; Lobkovsky, E. B.

In: Journal of the American Chemical Society, Vol. 118, No. 21, 01.01.1996, p. 5132-5133.

Research output: Contribution to journalArticle

Bonanno, JB, Henry, TP, Neithamer, DR, Wolczanski, PT & Lobkovsky, EB 1996, 'Arylamine C-N bond oxidative addition to (silox)3Ta (silox = (t)Bu3SiO)', Journal of the American Chemical Society, vol. 118, no. 21, pp. 5132-5133. https://doi.org/10.1021/ja960092l
Bonanno, Jeffrey B. ; Henry, T. P. ; Neithamer, D. R. ; Wolczanski, P. T. ; Lobkovsky, E. B. / Arylamine C-N bond oxidative addition to (silox)3Ta (silox = (t)Bu3SiO). In: Journal of the American Chemical Society. 1996 ; Vol. 118, No. 21. pp. 5132-5133.
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AU - Wolczanski, P. T.

AU - Lobkovsky, E. B.

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